Journal cover Journal topic
Climate of the Past An interactive open-access journal of the European Geosciences Union
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
Research article
18 Nov 2011
Review status
This discussion paper is a preprint. It has been under review for the journal Climate of the Past (CP). A final paper in CP is not foreseen.
First continuous phosphate record from Greenland ice cores
H. A. Kjær1, A. Svensson1, P. Vallelonga1, E. Kettner1, S. Schüpbach2, M. Bigler2, J. P. Steffensen1, and M. E. Hansson3 1Centre for Ice and Climate, Niels Bohr Institute, University of Copenhagen, Juliane Maries vej 30, 2100 Copenhagen, Denmark
2Climate and Environmental Physics, Physics Institute and Oeschger Centre for Climate Change Research, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland
3Physical Geography and Quaternary Geology, Stockholm University, Stockholm, Sweden
Abstract. A continuous and highly sensitive absorption method for detection of soluble phosphate in ice cores has been developed using a molybdate reagent and a 2 m liquid waveguide (LWCC). The method is optimized to meet the low concentrations of phosphate in Greenland ice, it has a detection limit of around 0.1 ppb and a depth resolution of approximately 2 cm. The new method has been applied to obtain phosphate concentrations from segments of two Northern Greenland ice cores: from a shallow firn core covering the most recent 120 yr and from the recently obtained deep NEEM ice core in which sections from the late glacial period have been analysed. Phosphate concentrations in 20th century ice are around 0.32 ppb with no indication of anthropogenic influence in the most recent ice. In the glacial part of the NEEM ice core concentrations in the cold stadial periods are significantly higher, in the range of 6–24 ppb, while interstadial ice concentrations are around 2 ppb. In the shallow firn core, a strong correlation between concentrations of phosphate and insoluble dust suggests a similar deposition pattern for phosphate and dust. In the glacial ice, phosphate and dust also correlate quite strongly, however it is most likely that this correlation originates from the phosphate binding to dust during transport, with only a fraction coming directly from dust. Additionally a constant ratio between phosphate and potassium concentrations shows evidence of a possible biogenic land source.

Please note: The technique for continuous phosphate determination reported here has been subsequently improved and published in Environmental Science & Technology. The technique reported here determines an unquantifiable mixture of soluble and insoluble phosphate, and hence may lead to variable phosphate recoveries from in ice core samples from different climatic periods. This deficiency has been avoided in the Environ. Sci. Technol. publication, by filtering insoluble particles from the sample before the addition of a reagent.

Citation: Kjær, H. A., Svensson, A., Vallelonga, P., Kettner, E., Schüpbach, S., Bigler, M., Steffensen, J. P., and Hansson, M. E.: First continuous phosphate record from Greenland ice cores, Clim. Past Discuss., 7, 3959-3989,, 2011.
H. A. Kjær et al.
Interactive discussionStatus: closed
AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment
Printer-friendly Version - Printer-friendly version      Supplement - Supplement
RC C2187: 'Review of Kjaer et al.', Michael Krom, 09 Jan 2012 Printer-friendly Version 
RC C2445: 'Comments on Kjaer et al.: Fisrt continuous phosphate record from Greenland ice cores', Anonymous Referee #2, 25 Jan 2012 Printer-friendly Version 
H. A. Kjær et al.
H. A. Kjær et al.


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