www.clim-past-discuss.net/7/2217/2011/ doi:10.5194/cpd-7-2217-2011 © Author(s) 2011. This work is distributed under the Creative Commons Attribution 3.0 License. Towards orbital dating of the EPICA Dome C ice core using δO2/N2 1Institut Pierre-Simon Laplace/Laboratoire des Sciences du Climat et de l'Environnement, UMR8212, CNRS – CEA-CNRS-UVSQ, 91191, Gif-sur-Yvette, France 2Université catholique de Louvain, Earth and Life Institute, Georges Lemaître Centre for Earth and Climate Research (TECLIM), Chemin du cyclotron, 2, 1348 Louvain la Neuve, Belgium 3Laboratoire de Glaciologie et Géophysique de l'Environnement, CNRS-UJF, 38402 St Martin d'Hères, France 4Arctic and Antarctic Research Institute, 38 Bering street, St Petersburg 199397, Russia 5Climate and Environmental Physics, Physics Institute, and Oeschger Centre for Climate Change Research, University of Bern, Sidlerstrasse 5, 3012 Bern, Switzerland *now at: American Association for the Advancement of Science (AAAS) Science & Technology Policy Fellow at the National Oceanic and Atmospheric Administration, 1401 Constitution Avenue NW, Washington, DC 20230, USA **now at: British Antarctic Survey, High Cross, Madingley Road, Cambridge, CB3 0ET, UK ***The two first authors participated equally to this work. Abstract. Based on a composite of several measurement series performed on ice samples stored at −25 °C or −50 °C, we present and discuss the first δO2/N2 record of trapped air from the EPICA Dome C (EDC) ice core covering the period between 300 and 800 ka (thousands of years before present). The samples stored at −25 °C show clear gas loss affecting the precision and mean level of the δO2/N2 record. Two different gas loss corrections are proposed to account for this effect, without altering the spectral properties of the original datasets. Although processes at play remain to be fully understood, previous studies have proposed a link between surface insolation, ice grain properties at close-off and δO2/N2 in air bubbles, from which an orbitally tuned chronologies of the Vostok and Dome Fuji ice core records have been derived over the last four climatic cycles. Here, we show that limitations caused by data quality and resolution, data filtering and uncertainties in the orbital tuning target limit the precision of this tuning method for EDC to at least 2.5 kyrs (thousands of years). Moreover, our extended record includes two periods of low eccentricity. During these intervals (around 400 ka and 750 ka), the matching between δO2/N2 and the different insolation curves is ambiguous because some local insolation maxima cannot be identified in the δO2/N2 record (and vice versa). Recognizing these limitations, we restrict the use of our δO2/N2 record to show that the EDC3 age scale is generally correct within its published uncertainty (6 kyrs) over the 300–800 ka period. We illustrate the uncertainties associated with data quality, filtering and tuning target for periods of low eccentricity by highlighting the difficulty to constrain the duration of Marine Isotopic Stage 11 based on the EDC δO2/N2 information. Discussion Paper (PDF, 1739 KB) Interactive Discussion (Closed, 5 Comments) Final Revised Paper (CP) Citation: Landais, A., Dreyfus, G., Capron, E., Pol, K., Loutre, M. F., Raynaud, D., Lipenkov, V. Y., Arnaud, L., Masson-Delmotte, V., Paillard, D., Jouzel, J., and Leuenberger, M.: Towards orbital dating of the EPICA Dome C ice core using δO2/N2, Clim. Past Discuss., 7, 2217-2259, doi:10.5194/cpd-7-2217-2011, 2011. Bibtex EndNote Reference Manager XML |