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	<journal>
		<journal_title>Climate of the Past Discussions</journal_title>
		<journal_url>www.clim-past-discuss.net</journal_url>
		<issn>1814-9340</issn>
		<eissn>1814-9359</eissn>
		<volume_number>6</volume_number>
		<issue_number>4</issue_number>
		<publication_year>2010</publication_year>
	</journal>
	<doi>10.5194/cpd-6-1473-2010</doi>
	<article_url>http://www.clim-past-discuss.net/6/1473/2010/</article_url>
	<abstract_html>http://www.clim-past-discuss.net/6/1473/2010/cpd-6-1473-2010.html</abstract_html>
	<fulltext_pdf>http://www.clim-past-discuss.net/6/1473/2010/cpd-6-1473-2010.pdf</fulltext_pdf>
	<start_page>1473</start_page>
	<end_page>1501</end_page>
	<publication_date>2010-08-11</publication_date>
	<article_title content_type="html">Rapid changes in ice core gas records – Part 2: Understanding the rapid rise in atmospheric  CO&lt;sub&gt;2&lt;/sub&gt; at the onset of the Bølling/Allerød</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>P. Köhler</name>
			<email>peter.koehler@awi.de</email>
		</author>
		<author numeration="2" affiliations="1,2">
			<name>G. Knorr</name>
		</author>
		<author numeration="3" affiliations="3">
			<name>D. Buiron</name>
		</author>
		<author numeration="4" affiliations="3,4">
			<name>A. Lourantou</name>
		</author>
		<author numeration="5" affiliations="3">
			<name>J. Chappellaz</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Alfred Wegener Institute for Polar and Marine Research (AWI), P.O. Box 120161, 27515 Bremerhaven, Germany</affiliation>
		<affiliation numeration="2" content_type="html">School of Earth and Ocean Sciences, Cardiff University, Cardiff, Wales, UK</affiliation>
		<affiliation numeration="3" content_type="html">Laboratoire de Glaciologie et Géophysique de l&apos;Environnement, (LGGE, CNRS, Université Joseph Fourier-Grenoble),  54b rue Molière, Domaine Universitaire BP 96, 38402 St. Martin d&apos;Hères,  France</affiliation>
		<affiliation numeration="4" content_type="html">now at: Laboratoire d&apos;Océanographie et du Climat (LOCEAN), Institut Pierre Simon Laplace,  Université P. et M. Curie (UPMC), Paris, France</affiliation>
	</affiliations>
	<abstract content_type="html">During the last glacial/interglacial transition the Earth&apos;s climate underwent rapid changes
      around 14.6 kyr ago. Temperature proxies from ice cores revealed the onset of the
      Bølling/Allerød (B/A) warm period in the north and the start of the Antarctic Cold
      Reversal in the south. Furthermore, the B/A is accompanied by a rapid sea level rise of
      about 20 m during meltwater pulse (MWP) 1A, whose exact timing is matter of current
      debate. In situ measured CO&lt;sub&gt;2&lt;/sub&gt; in the EPICA Dome C (EDC) ice core also revealed
      a remarkable jump of 10&amp;plusmn;1 ppmv in 230 yr at the same time. Allowing for the age
      distribution of CO&lt;sub&gt;2&lt;/sub&gt; in firn we here show, that atmospheric CO&lt;sub&gt;2&lt;/sub&gt; rose by
      20–35 ppmv in less than 200 yr, which is a factor of 2–3.5 larger than the
      CO&lt;sub&gt;2&lt;/sub&gt; signal recorded in situ in EDC. Based on the estimated airborne fraction
      of 0.17 of CO&lt;sub&gt;2&lt;/sub&gt; we infer that 125 Pg of carbon need to be released to the
      atmosphere to produce such a peak. Most of the carbon might have been activated as
      consequence of continental shelf flooding during MWP-1A.  This impact of rapid sea level
      rise on atmospheric CO&lt;sub&gt;2&lt;/sub&gt; distinguishes the B/A from other Dansgaard/Oeschger events
      of the last 60 kyr, potentially defining the point of no return during the last
      deglaciation.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Ahn,~J. and Brook,~E J.: Atmospheric \chemCO_2 and climate on millennial time scales during the last glacial period, Science, 322, 83–85, \doi10.1126/science.1160832, 2008. </reference>
		<reference numeration="2" content_type="text"> Ahn,~J., Wahlen,~M., Deck,~B L., Brook,~E J., Mayewski,~P A., Taylor,~K C., and White,~J W C.: A~record of atmospheric \chemCO_2 during the last 40 000 years from the Siple Dome, Antarctica ice core, J. Geophys. Res., 109, D13305, \doi10.1029/2003JD004415, 2004. </reference>
		<reference numeration="3" content_type="text"> Barker,~S., Diz,~P., Vantravers,~M J., Pike,~J., Knorr,~G., Hall,~I R., and Broecker,~W S.: Interhemispheric Atlantic seesaw response during the last deglaciation, Nature, 457, 1007–1102, \doi10.1038/nature07770, 2009. </reference>
		<reference numeration="4" content_type="text"> Boyle,~E A.: Cadmium and $\delta\chem^13C$ paleochemical ocean distributions during the stage 2 glacial maximum, Ann. Rev. Earth Planet. Sci., 20, 245–287, 1992. </reference>
		<reference numeration="5" content_type="text"> Collatz,~G J., Berry,~J A., and Clark,~J S.: Effects of climate and atmospheric \chemCO_2 partial pressure on the global distribution of \chemC_4 grasses: present, past and future, Oecologia, 114, 441–454, 1998. </reference>
		<reference numeration="6" content_type="text"> Deschamps,~P., Durand,~N., Bard,~E., Hamelin,~B., Camoin,~G., Thomas,~A., Henderson,~G., and Yokoyama,~Y.: Synchroneity of Meltwater Pulse 1A and the Bolling onset: New evidence from the IODP Tahiti Sea-Level Expedition, Geophys. Res. Abstr., 11, EGU22009–10233, 2009. </reference>
		<reference numeration="7" content_type="text"> EPICA-community-members: One-to-one coupling of glacial climate variability in Greenland and Antarctica, Nature, 444, 195–198, \doi10.1038/nature05301, 2006. </reference>
		<reference numeration="8" content_type="text"> Fischer,~H., Behrens,~M., Bock,~M., Richter,~U., Schmitt,~J., Loulergue,~L., Chappellaz,~J., Spahni,~R., Blunier,~T., Leuenberger,~M., and Stocker,~T F.: Changing boreal methane sources and constant biomass burning during the last termination, Nature, 452, 864–867, \doi10.1038/nature06825, 2008. </reference>
		<reference numeration="9" content_type="text"> Goujon,~C., Barnola,~J.-M., and Ritz,~C.: Modeling the densification of polar firn including heat diffusion: Application to close-off characteristics and gas isotopic fractionation for Antarctica and Greenland sites, J. Geophys. Res., 108, 4792, \doi10.1029/2002JD003319, 2003. </reference>
		<reference numeration="10" content_type="text"> Hanebuth,~T., Stattegger,~K., and Grootes,~P M.: Rapid flooding of the Sunda Shelf: a~late-glacial sea-level record, Science, 288, 1033–1035, \doi10.1126/science.288.5468.1033, 2000. </reference>
		<reference numeration="11" content_type="text"> Joos,~F. and Spahni,~R.: Rates of change in natural and anthropogenic radiative forcing over the past 20 000 years, Proc. Natl. Acad. Sci., 105, 1425–1430, \doi10.1073/pnas.0707386105, 2008. </reference>
		<reference numeration="12" content_type="text"> Keeling,~R F., Piper,~S., Bollenbacher,~A., and Walker,~J.: Atmospheric \chemCO_2 records from sites in the SIO air sampling network, in: Trends: A~Compendium of Data on Global Change, Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory,~US Department of Energy, Oak Ridge, Tenn., USA, 2009. </reference>
		<reference numeration="13" content_type="text"> Kienast,~M., Hanebuth,~T., Pelejero,~C., and Steinke,~S.: Synchroneity of meltwater pulse 1a and the Bølling warming: New evidence from the South China Sea, Geology, 31, 67–70, 2003. </reference>
		<reference numeration="14" content_type="text"> Köhler,~P.: Rapid changes in ice core gas records – Part 1: On the accuracy of methane synchronisation of ice cores, Clim. Past Discuss., 6, 1453–1471, doi:10.5194/cpd-6-1453-2010, 2010. </reference>
		<reference numeration="15" content_type="text"> Köhler,~P. and Fischer,~H.: Simulating changes in the terrestrial biosphere during the last glacial/interglacial transition, Global Planet. Change, 43, 33–55, \doi10.1016/j.gloplacha.2004.02.005, 2004. </reference>
		<reference numeration="16" content_type="text"> Köhler,~P., Fischer,~H., Munhoven,~G., and Zeebe,~R E.: Quantitative interpretation of atmospheric carbon records over the last glacial termination, Global Biogeochem. Cy., 19, GB4020, \doi10.1029/2004GB002345, 2005a. </reference>
		<reference numeration="17" content_type="text"> Köhler,~P., Joos,~F., Gerber,~S., and Knutti,~R.: Simulated changes in vegetation distribution, land carbon storage, and atmospheric \chemCO_2 in response to a~collapse of the North Atlantic thermohaline circulation, Clim. Dynam., 25, 689–708, \doi10.1007/s00382-005-0058-8, 2005b. </reference>
		<reference numeration="18" content_type="text"> Köhler,~P., Bintanja,~R., Fischer,~H., Joos,~F., Knutti,~R., Lohmann,~G., and Masson-Delmotte,~V.: What caused Earth&apos;s temperature variations during the last 800 000 years? Data-based evidences on radiative forcing and constraints on climate sensitivity, Quaternary Sci. Rev., 29, 129–145, \doi10.1016/j.quascirev.2009.09.026, 2010a. </reference>
		<reference numeration="19" content_type="text"> Köhler,~P., Fischer,~H., and Schmitt,~J.: Atmospheric $\delta\chem^13CO_2$ and its relation to \chem\textitpCO_2 and deep ocean $\delta\chem^13C$ during the late Pleistocene, Paleoceanography, 25, PA1213, \doi10.1029/2008PA001703, 2010b. </reference>
		<reference numeration="20" content_type="text"> Kroopnick,~P M.: The distribution of \chem^13C of $\sum \chemCO_2$ in the world oceans, Deep-Sea Res. Pt. I, 32, 57–84, 1985. </reference>
		<reference numeration="21" content_type="text"> Le Quéré,~C., Raupach,~M R., Canadell,~J G., Marland,~G., Bopp,~L., Ciais,~P., Conway,~T J., Doney,~S C., Feely,~R A., Foster,~P., Friedlingstein,~P., Gurney,~K., Houghton,~R A., House,~J I., Huntingford,~C., Levy,~P E., Lomas,~M R., Majku,~J., Metz,~N., Ometto,~J P., Peters,~G P., Prentice,~I C., Randerson,~J T., Running,~S W., Sarmiento,~J L., Schuster,~U., Sitch,~S., Takahashi,~T., Viovy,~N., van~der Werf,~G R., and Woodward,~F I.: Trends in the sources and sinks of carbon dioxide, Nat. Geosci., 2, 831–836, \doi10.1038/ngeo689, 2009. </reference>
		<reference numeration="22" content_type="text"> Lemieux-Dudon,~B., Blayo,~E., Petit,~J.-R., Waelbroeck,~C., Svensson,~A., Ritz,~C., Barnola,~J.-M., Narcisi,~B M., and Parrenin,~F.: Consistent dating for Antarctic and Greenland ice cores, Quaternary Sci. Rev., 29, 8–20, \doi10.1016/j.quascirev.2009.11.010, 2010. </reference>
		<reference numeration="23" content_type="text"> Lenton,~T M., Held,~H., Kriegler,~E., Hall,~J W., Lucht,~W., Rahmstorf,~S., and Schellnhuber,~H J.: Tipping elements in the Earth&apos;s climate system, Proc. Natl. Acad. Sci., 105, 1786–1793, \doi10.1073/pnas.0705414, 105, 2008. </reference>
		<reference numeration="24" content_type="text"> Lloyd,~J. and Farquhar,~G D.: \chem^13C discrimination during \chemCO_2 assimilation by the terrestrial biosphere, Oecologia, 99, 201–215, 1994. </reference>
		<reference numeration="25" content_type="text"> Lourantou,~A., Lavrič,~J V., Köhler,~P., Barnola,~J.-M., Michel,~E., Paillard,~D., Raynaud,~D., and Chappellaz,~J.: Constraint of the \chemCO_2 rise by new atmospheric carbon isotopic measurements during the last deglaciation, Global Biogeochem. Cy., 24, GB2015, \doi10.1029/2009GB003545, 2010. </reference>
		<reference numeration="26" content_type="text"> Monnin,~E., Indermühle,~A., Dällenbach,~A., Flückiger,~J., Stauffer,~B., Stocker,~T F., Raynaud,~D., and Barnola,~J.-M.: Atmospheric \chemCO_2 concentrations over the last glacial termination, Science, 291, 112–114, 2001. </reference>
		<reference numeration="27" content_type="text"> NorthGRIP-members: High-resolution record of Northern Hemisphere climate extending into the last interglacial period, Nature, 431, 147–151, 2004. </reference>
		<reference numeration="28" content_type="text"> Peltier,~W R.: On the hemispheric origin of meltwater pulse 1a, Quaternary Sci. Rev., 24, 1655–1671, 2005. </reference>
		<reference numeration="29" content_type="text"> Peltier,~W R. and Fairbanks,~R G.: Global glacial ice volume and Last Glacial Maximum duration from an extended Barbados sea level record, Quaternary Sci. Rev,, 25, 3322–3337, \doi10.1016/j.quascirev.2006.04.010, 2007. </reference>
		<reference numeration="30" content_type="text"> Sabine,~C L., Feely,~R A., Gruber,~N., Key,~R M., Lee,~K., Bullister,~J L., Wanninkhof,~R., Wong,~C S., Wallace,~D W R., Tilbrook,~B., Millero,~F J., Peng,~T.-H., Kozyr,~A., Ono,~T., and Rios,~A F.: The oceanic sink for anthropogenic \chemCO_2, Science, 305, 367–371, 2004a. </reference>
		<reference numeration="31" content_type="text"> Sabine,~C L., Heimann,~M., Artaxo,~P., Bakker,~D C E., Arthur,~C.-T., Field,~C B., Gruber,~N., Le Quéré,~C., Prinn,~R G., Richey,~J E., Lankao,~P R., Sathaye,~J A., and Valentini,~R.: Current status and past trends of the global carbon cycle, in: The Global Carbon Cycle: Integrating Humans, Climate, and the Natural World, edited by: Field,~C B. and Raupach,~M R., Island Press, Washington, Covelo, London, 17–44, 2004b. </reference>
		<reference numeration="32" content_type="text"> Schmittner,~A. and Galbraith,~E D.: Glacial greenhouse-gas fluctuations controlled by ocean circulation changes, Nature, 456, 373–376, \doi10.1038/nature07531, 2008. </reference>
		<reference numeration="33" content_type="text"> Scholze,~M., Kaplan,~J O., Knorr,~W., and Heimann,~M.: Climate and interannual variability of the atmosphere-biosphere \chem^13CO_2 flux, Geophys. Res. Lett., 30, 1097, \doi10.1029/2002GL015631, 2003. </reference>
		<reference numeration="34" content_type="text"> Siddall,~M., Rohling,~E J., Thompson,~W G., and Waelbroeck,~C.: Marine isotope stage 3 sea level fluctuations: data synthesis and new outlook, Rev. Geophys., 46, RG4003, \doi10.1029/2007RG000226, 2008. </reference>
		<reference numeration="35" content_type="text"> Siegenthaler,~U. and Münnich,~K O.: \chem^13C/\chem^12C fractionation during \chemCO_2 transfer from air to sea, in: Carbon Cycle Modelling, edited by: Bolin,~B., vol 16 of SCOPE, Wiley and Sons, Chichester, NY, 249–257, 1981. </reference>
		<reference numeration="36" content_type="text"> Smith,~H J., Fischer,~H., Wahlen,~M., Mastroianni,~D., and Deck,~B.: Dual modes of the carbon cycle since the Last Glacial Maximum, Nature, 400, 248–250, 1999. </reference>
		<reference numeration="37" content_type="text"> Smith,~W H. and Sandwell,~D T.: Global sea floor topography from satellite altimetry and ship depth soundings, Science, 277, 1956–1962, \doi10.1126/science.277.5334.1956, 1997. </reference>
		<reference numeration="38" content_type="text"> Spahni,~R., Chappellaz,~J., Stocker,~T F., Loulergue,~L., Hausammann,~G., Kawamura,~K., Flückiger,~J., Schwander,~J., Raynaud,~D., Masson-Delmotte,~V., and Jouzel,~J.: Atmospheric methane and nitrous oxide of the late Pleistocene from Antarctic ice cores, Science, 310, 1317–1321, \doi10.1126/science.1120132, 2005. </reference>
		<reference numeration="39" content_type="text"> Stanford,~J D., Rohling,~E J., Hunter,~S E., Roberts,~A P., Rasmussen,~S O., Bard,~E., McManus,~J., and Fairbanks,~R G.: Timing of meltwater pulse 1a and climate responses to meltwater injections, Paleoceanography, 21, PA4103, \doi10.1029/2006PA001340, 2006. </reference>
		<reference numeration="40" content_type="text"> Steffensen,~J P., Andersen,~K K., Bigler,~M., Clausen,~H B., Dahl-Jensen,~D., Fischer,~H., Goto-Azuma,~K., Hansson,~M., Johnsen,~S J., Jouzel,~J., Masson-Delmotte,~V., Popp,~T., Rasmussen,~S O., Rothlisberger,~R., Ruth,~U., Stauffer,~B., Siggaard-Andersen,~M.-L., Sveinbjörnsdóttir,~A E., Svensson,~A., and White,~J W C.: High-resolution Greenland ice core data show abrupt climate change happens in few years, Science, 321, 680–684, \doi10.1126/science.1157707, 2008. </reference>
		<reference numeration="41" content_type="text"> Stenni,~B., Masson-Delmotte,~V., Johnsen,~S., Jouzel,~J., Longinelli,~A., Monnin,~E., Röthlisberger,~R., and Selmo,~E.: An oceanic cold reversal during the last deglaciation, Science, 293, 2074–2077, 2001. </reference>
		<reference numeration="42" content_type="text"> Thompson,~W G. and Goldstein,~S L.: A~radiometric calibration of the SPECMAP timescale, Quaternary Sci. Rev., 25, 3207–3206, \doi10.1016/j.quascirev.2006.02.007, 2007. </reference>
		<reference numeration="43" content_type="text"> Zeng, N.: Quasi-100 ky glacial-interglacial cycles triggered by subglacial burial carbon release, Clim. Past, 3, 135–153, doi:10.5194/cp-3-135-2007, 2007. </reference>
	</references>
</article>

